Study on the composite Nd：YAG crystal by laser micro- Raman spectroscopy

The composite Nd:YAG crystal with undoped YAG end caps was fabricated by thermal bonding technique. Scanning electron microscopy (SEM) result shows that the width of the bonded interface was about 0.5 μm. The laser micro-Raman was used to study the bonded interface of the composite crystal. The results of Raman spectra and the bonded interface image indicate that the undoped YAG and Nd:YAG crystals have been well bonded together. Furthermore, it can be drawn that the structure and the composition of the bonded interface are the same as the undoped YAG crystal, and that the Nd3 ions do not enter the bonded interface and the YAG side. This property is advantageous to decrease the thermal effect of the boned interface and to improve the laser stability.     

亚稳态惰性原子与SOCl_2传能反应产物SO(A)的发射光谱和强度分析

本文在流动余辉装置上,利用亚稳态惰性气体原子[He(2~3S)、Ne(~3P_(0,2))、Ar(~3P_(0,2))]与SOCl_2的专能反应,在(230-430nm)波段观察到了产物的发射谱,光谱归属为自由基SO(A~3∏_(2,1,0)→X~3∑~-)的跃迁。对光谱强度分析表明:SO(A→X)的偶极跃迁矩Re随核间距明显地变化。通过拟合,找出了这一变化的关系。另外,本文还计算了SO(A~3∏_0→X~3∑~-)跃迁的Franck-Condon因子。     

Systematical study on the roles of transition alloying substitutions on anti-disproportionation reaction of ZrCo during charging and releasing hydrogen

Intermetallic alloy ZrCo is believed to be a good substitution for uranium to store tritium. Nevertheless, disproportionation reaction often happens during the hydriding and dehydriding processes, and hydrogen storage property of ZrCo is therefore degraded. Alloying elements are often used to substitute Zr or Co in ZrCo to restrain disproportionation reaction. However, many experimental results do not agree with each other, and it lacks overall tendency for all transition metal elements. In this work, systematical ab initio calculations are performed to study more than 20 transition alloying elements to substitute Co and Zr in ZrCoH₃ to study the anti-disproportionation effects. It is found that substitution of Co by transition metal elements on anti-disproportionation reaction is unconspicuous, and only Ni can enlarge Zr–H bond length and decrease the volume of 8e site, presenting anti-disproportionation effect, which qualitatively agrees with the previous experiments. In contrast, all transition alloying elements considered except Fe, Co, Ni, Ru, Rh, Pd, Os and Ir replacing Zr can both enlarge the length of Zr–H bond and decrease the volume of 8e site, and thus restrain the disproportionation effects. At last, two-dimensional charge density and density of states are calculated to analyze the underlying mico-mechanisms affecting the effects of transition alloying elements on anti-disproportionation reaction.     

基于PLC控制的双头车床主电路设计

我国大多数机床主电路采用的是继电器控制,近10年来,随着PLC价格的不断降低和用户需求的不断扩大,越来越多的中小设备开始采用PLC进行控制。采用PLC控制替换传统继电器控制,可以提高机床设备的技术水平与性能,使机床设备获得技术升级,相同I/O点数的控制系统,用PLC控制比用传统的继电器控制,其成本要低大约40%左右。PLC没有专用操作站,它用的软件和硬件都是通用的,所以维护成本比继电器要低很多。一个PLC的控制器,可以接收几千个I/O点(最多可达8000多个I/O)。如果被控对象主要是设备连锁、回路很少,采用PLC较为合适。PLC在我国的应用增长十分迅速。随着中国经济的高速发展和基础自动化水平的不断提高,今后一段时期内PLC在我国仍将保持高速增长势头。通过对YX-C46中间驱动双头车床的数控化改造,提出基于PLC控制的双头车床主电路设计新思路。     

微弱光电流信号放大器的设计

针对等离子体物理实验装置托卡马克(EAST)实验中微弱信号的探测需要,结合EAST的恶劣电磁环境以及光电检测电路的基本工作原理,设计了一种实用的光电弱信号电流放大器.电路由前置电流放大器、有源滤波放大电路构成,结合电磁兼容技术对信号进行接地和屏蔽,以及合理布线,旨在保证增益和带宽的同时降低噪声.实验表明,基于本设计的光...     

非线性规划神经网络模型

本文提出一种求解闭凸集上非线性规划问题的神经网络模型,给出了它的Liapunov函数,在适当的假设下,运用La Salle不变性原理证明了它的大范围渐近稳定性,并给出了计算机模拟。     

Non-stoichiometric tungsten-carbide-oxide-supported Pt–Ru anode catalysts for PEM fuel cells – From basic electrochemistry to fuel cell performance

Durability and cost of Proton Exchange Membrane fuel cells (PEMFCs) are two major factors delaying their commercialization. Cost is associated with the price of the catalysts, while durability is associated with degradation and poisoning of the catalysts, primarily by CO. This motivated us to develop tungsten-carbide-oxide (W_xC_yO_z) as a new non-carbon based catalyst support for Pt–Ru–based anode PEMFC catalyst. The aim was to improve performance and obtain higher CO tolerance compared to commercial catalysts. The performance of obtained PtRu/W_xC_yO_z catalysts was investigated using cyclic voltammetry, linear scan voltammetry and rotating disk electrode voltammetry. Particular attention was given to the analysis of CO poisoning, to better understand how W_xC_yO_z species can contribute to the CO tolerance of PtRu/W_xC_yO_z. Improved oxidation of CO_ads at low potentials (E < 0.5 V vs. RHE) was ascribed to OH provided by the oxide phase at the interfacial region between the support and the PtRu particles. On the other hand, at high potentials (E > 0.5 V vs. RHE) CO removal proceeds dominantly via OH provided from the oxidized metal sites. The obtained catalyst with the best performance (30% PtRu/W_xC_yO_z) was tested as an anode catalyst in PEM fuel cell. When using synthetic reformate as a fuel in PEMFC, there is a significant power drop of 35.3 % for the commercial 30% PtRu/C catalyst, while for the PtRu/W_xC_yO_z anode catalyst this drop is around 16 %.     

Enhanced thermodynamic properties of ZrNiH3 by substitution with transition metals (V,Ti, Fe,Mn and Cr)

First-principles calculations based on Plane-Wave Self-Consistent Field (PWSCF) method, implemented in quantum espresso program, have been performed on ZrNiH₃ substituted with transition metals (V, Ti, Fe, Mn, and Cr). The study aims to investigate the heat of formation in terms of material stability and desorption temperature. It is found that the substitution by transition metals, results in a significant enhancement in the thermodynamic properties accompanied by an increase of the volumetric and gravimetric hydrogen storage capacities. In addition, the obtained values of heat of formation and desorption temperature corroborate with that required by the U.S. Department of Energy (DOE) for stability and volumetric capacity criteria. Moreover, Mn and Fe elements are found to present the lowest substituting content (34%) to obtain optimum hydrogen storage characteristics (enthalpy of formation of - 40 kJ/mol.H₂, decomposition temperature of 300 K and volumetric capacity of 134 g.H₂/l), without affecting the electronic structure and the metallic character of ZrNiH₃.     

First principle investigation on hydrogen solid storage in Zr1-xNbxNiH3 (x = 0 and 0.1)

We study hydrogen storage properties of Nb doped ZrNiH₃ using the first-principles calculations based on density functional theory (DFT). To achieve such calculations, we used full potential linearized augmented plane waves (FP-LAPW) method implanted in WIEN2K code. Total energy and density of states (DOS) are computed for Zr_1-xNb_xNiH₃ (x = 0 and 0.1). It turns out that substituting 10% of zirconium by niobium in ZrNiH₃ matrix involves a destabilization of the system. This destabilization is induced by the formation of a new hybridization between niobium and hydrogen atoms. Furthermore, the thermodynamic stability in terms of its energy of formation, as well as the capacity of the material to store hydrogen are discussed. Noteworthy that from FP-LAPW we report that Nb doped ZrNiH₃ lower the desorption temperature to 305.77 K without significant reduction of the hydrogen storage capacity. This lowering of the temperature desorption makes the material very useful for hydrogen storage in solids.     

基于高校公共机房管理系统的设计与实现

本文针对高校公共机房的管理特点,结合安徽经济管理干部学院现代教育中心公共机房的现状,对课程安排、有效管理和开放计费做了大量研究。主要目的一是便于同学们更加有效、安全、便利的上机进行课程实践;二是提高机房的科学管理水平,同时减轻机房管理的工作量。开发过程中运用了VC++数据库编程、网络编程等核心技术。基本实现预定目标。体现了该系统的界面友好、实现简洁、运行高效和维护方便等特点。